Effect of pore size on the performance of mesoporous material supported chiral Mn (III) salen complex for the epoxidation of unfunctionalized olefins
K Yu, Z Gu, R Ji, LL Lou, F Ding, C Zhang, S Liu
Index: Yu, Kai; Gu, Zhicheng; Ji, Runan; Lou, Lan-Lan; Ding, Fei; Zhang, Cui; Liu, Shuangxi Journal of Catalysis, 2007 , vol. 252, # 2 p. 312 - 320
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Citation Number: 55
Abstract
A series of mesoporous MCM-41 and MCM-48 materials with different pore sizes were synthesized and used as supports to immobilize chiral Mn (III) salen complex. The heterogeneous catalysts were characterized by XRD, FT-IR, DR UV–vis, and N2 sorption, and the results indicated the successful immobilization of chiral Mn (III) salen complex. The confinement effect of pore size on the catalytic performance of the heterogeneous ...
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