Crown??Tetrathiafulvalenes Attached to a Pyrrole or an EDOT Unit: Synthesis, Electropolymerization and Recognition Properties

…, J Lyskawa, M Mazari, J Roncali…

Index: Trippe, Gaelle; Le Derf, Franck; Lyskawa, Joel; Mazari, Miloud; Roncali, Jean; Gorgues, Alain; Levillain, Eric; Salle, Marc Chemistry - A European Journal, 2004 , vol. 10, # 24 p. 6497 - 6509

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Citation Number: 63

Abstract

Abstract A crown-tetrathiafulvalene electroactive receptor has been covalently linked to electropolymerizable pyrrole or 3, 4-ethylenedioxythiophene monomers. The synthetic route to the monofonctionalized tetrathiafulvalene (TTF) ligand has been optimized. Two derivatives of pyrrole (N-and 3-substituted) were synthesized. The various substituted monomers have been electropolymerized to produce polypyrrole (PP) and poly ( ...