Palladium??Catalyzed [3, 3] Sigmatropic Rearrangement of (Allyloxy) iminodiazaphospholidines: Allylic Transposition of C O and C N Functionality
EE Lee, RA Batey
Index: Lee, Ernest E.; Batey, Robert A. Angewandte Chemie - International Edition, 2004 , vol. 43, # 14 p. 1865 - 1868
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Citation Number: 32
Abstract
The principle of driving reactions thermodynamically through the conversion of PIII reagents into PV= O products is well established, as exemplified by the Wittig and Mitsunobu reactions, and the [2, 3] sigmatropic rearrangement of allyl phosphites into allyl phosphonates.[1] Herein we describe a novel [3, 3] sigmatropic rearrangement in which allylic transposition is driven by a PV= N to PV= O interconversion (Scheme 1). We ...
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