Reaction of superoxide with phenoxyl-type radicals
N d'Alessandro, G Bianchi, X Fang, F Jin…
Index: d'Alessandro, Nicola; Bianchi, Giorgio; Fang, Xingwang; Jin, Famin; Schuchmann, Heinz-Peter; Von Sonntag, Clemens Journal of the Chemical Society. Perkin Transactions 2, 2000 , # 9 p. 1862 - 1867
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Citation Number: 37
Abstract
Radiolytically generated phenoxyl radicals derived from the structurally similar phenols cresol, tyrosine, tyramine and tyrosol were reacted with O2˙−[k=(1–4.5)× 109 dm3 mol− 1 s− 1, by pulse radiolysis] and the consumption of the phenol determined. Although the reduction potentials of these phenoxyl radicals are very close, ranging between+ 0.64 and+ 0.68 V, the yields of phenol consumption vary considerably [between 8%(tyrosol) and 90 ...
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