Kinetics of the insertion of singlet methylene into methylfluorosilanes

TN Bell, AG Sherwood…

Index: Bell, T. N.; Sherwood, A. G.; Soto-Garrido, G. Journal of Physical Chemistry, 1986 , vol. 90, # 6 p. 1184 - 1186

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Citation Number: 2

Abstract

Conclusions NA undergoes one-electron reduction by e; and a-hydroxyalkyl radicals with reactivities which are strongly enhanced, with respect to other azobenzene derivatives, by the nitro substitution. In fact the rate constants of the reaction of NA with e;, both in i-PrOH and in MeOH, are higher than those found for A and DA in the same solvent^.^(CH,), COH gives electron transfer to NA with a rate constant k N lo9 M-'sI,? orders of magnitude faster ...