THE CONSTITUTION OF DISULFOXIDES1

H Gilman, LE Smith, HH Parker

Index: Gilman; Smith; Parker Journal of the American Chemical Society, 1925 , vol. 47, p. 858

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Citation Number: 23

Abstract

The first is the disulfoxide structure; the second is the anhydride structure, and represents the compound as a mixed anhydride of a sulfinic (RS02H) and a sulfenic (RSOH) acid; the third is the thiosulfonic ester structure, and relates the compounds to thiosulfonic acids (RSOtSH). In a recent paper by Smiles and GibsonJ2 an excellent summary with ample literature references presents the essential arguments for and against each of the three ...

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