Equilibrium shift in the rhodium-catalyzed acyl transfer reactions
…, T Yamada, K Bando, T Ichikawa, M Yamaguchi
Index: Arisawa, Mieko; Igarashi, Yui; Kobayashi, Haruki; Yamada, Toru; Bando, Kentaro; Ichikawa, Takuya; Yamaguchi, Masahiko Tetrahedron, 2011 , vol. 67, # 40 p. 7846 - 7859
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Citation Number: 20
Abstract
Rhodium/phosphine complexes catalyze equilibrium acyl transfer reactions between acid fluorides, aryl esters, acylphosphine sulfides, and thioesters. The use of appropriate co- substrates to accept heteroatom groups shifted the equilibrium to desired products. Acylphosphine sulfides and aryl esters were converted to acid fluorides using benzoylpentafluorobenzene as the fluoride donor, and the fluorination reaction of ...
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Equilibrium shift in the rhodium-catalyzed acyl transfer reactions
[Tetrahedron, , vol. 67, # 40 p. 7846 - 7859]