Tetrahedron: Asymmetry

Application of optically active 1, 2-diol monotosylates for synthesis of β-azido and β-amino alcohols with very high enantiomeric purity. Synthesis of enantiopure (R)- …

BT Cho, SK Kang, SH Shin

Index: Tae Cho, Byung; Kyu Kang, Sang; Hye Shin, Sung Tetrahedron Asymmetry, 2002 , vol. 13, # 11 p. 1209 - 1217

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Citation Number: 54

Abstract

Optically active β-azido alcohols are of great significance as potential precursors for non-racemic aziridines 1 and β-amino alcohols. 2 The latter compounds are not only a common structural component in a vast group of naturally occurring and synthetic molecules, but also can be widely used as versatile chiral building blocks and chiral catalysts 3 in organic synthesis. In particular, chiral 2-amino-1-arylethanols are important structural elements in ...

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