Chiral nanoporous metal–metallosalen frameworks for hydrolytic kinetic resolution of epoxides

C Zhu, G Yuan, X Chen, Z Yang…

Index: Zhu, Chengfeng; Yuan, Guozan; Chen, Xu; Yang, Zhiwei; Cui, Yong Journal of the American Chemical Society, 2012 , vol. 134, # 19 p. 8058 - 8061

Full Text: HTML

Citation Number: 132

Abstract

Chiral nanoporous metal–organic frameworks are constructed by using dicarboxyl- functionalized chiral Ni (salen) and Co (salen) ligands. The Co (salen)-based framework is shown to be an efficient and recyclable heterogeneous catalyst for hydrolytic kinetic resolution (HKR) of racemic epoxides with up to 99.5% ee. The MOF structure brings Co (salen) units into a highly dense arrangement and close proximity that enhances ...

Related Articles:

Cardiovascular hybrid drugs: new benzazepinone derivatives as bradycardic agents endowed with selective β 1-non-competitive antagonism

[Bisi, Alessandra; Rampa, Angela; Budriesi, Roberta; Gobbi, Silvia; Belluti, Federica; Ioan, Pierfranco; Valoti, Ermanno; Chiarini, Alberto; Valenti, Piero Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 7 p. 1353 - 1361]

Jacobsen-type enantioselective hydrolysis of aryl glycidyl ethers. 31P NMR analysis of the enantiomeric composition of oxiranes

[Bredikhin; Strunskaya; Novikova; Azancheev; Sharafutdinova; Bredikhina Russian Chemical Bulletin, 2004 , vol. 53, # 1 p. 213 - 218]

Highly Efficient Recyclable CoIII–salen Complexes in the Catalyzed Asymmetric Aminolytic Kinetic Resolution of Aryloxy/Terminal Epoxides for the Simultaneous …

[Kureshy, Rukhsana I.; Prathap, K. Jeya; Agrawal, Santosh; Kumar, Manish; Khan, Noor-Ul H.; Abdi, Sayed H. R.; Bajaj, Hari C. European Journal of Organic Chemistry, 2009 , # 17 p. 2863 - 2871]

Highly Efficient Recyclable CoIII–salen Complexes in the Catalyzed Asymmetric Aminolytic Kinetic Resolution of Aryloxy/Terminal Epoxides for the Simultaneous …

[Kureshy, Rukhsana I.; Prathap, K. Jeya; Agrawal, Santosh; Kumar, Manish; Khan, Noor-Ul H.; Abdi, Sayed H. R.; Bajaj, Hari C. European Journal of Organic Chemistry, 2009 , # 17 p. 2863 - 2871]

Cardiovascular hybrid drugs: new benzazepinone derivatives as bradycardic agents endowed with selective β 1-non-competitive antagonism

[Bisi, Alessandra; Rampa, Angela; Budriesi, Roberta; Gobbi, Silvia; Belluti, Federica; Ioan, Pierfranco; Valoti, Ermanno; Chiarini, Alberto; Valenti, Piero Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 7 p. 1353 - 1361]

More Articles...