Kinetics of the Rapid Dark Reaction between Methanol and Oxygen in the Presence of a" Photocatalyst"
NAM Zabidi, D Tapp, TF Thomas
Index: Mohd.Zabidi, Noor A.; Tapp, Dale; Thomas, Timothy F. Journal of Physical Chemistry, 1995 , vol. 99, # 40 p. 14733 - 14737
Full Text: HTML
Citation Number: 5
Abstract
It has been discovered that a rapid dark reaction occurs on adding platinized Ti02 “photocatalyst” to liquid methanol before and/or during degassing resulting in large amounts of formaldehyde (mostly in the form of methoxymethanol) being present at the start of subsequent photolyses. The kinetics of this reaction has been studied in a magnetically stirred reactor over the temperature range 282-325 K, yielding an activation energy ...
Related Articles:
Asymmetric synthesis of (−)-(R)-sitagliptin
[Davies, Stephen G.; Fletcher, Ai M.; Lv, Linlu; Roberts, Paul M.; Thomson, James E. Tetrahedron Letters, 2012 , vol. 53, # 24 p. 3052 - 3055]
Products and reaction routes in the diozonolysis of 2, 3-dimethyl-1, 3-butadiene in methanol
[Griesbaum, Karl; Zwick, Garhard; Agarwal, Sudhir; Keul, Helmut; Pfeffer, Bernd; Murray, Robert W. Journal of Organic Chemistry, 1985 , vol. 50, # 22 p. 4194 - 4199]
Dual Reactivity of Methoxymethyl Benzenesulfenate in Nucleophilic Substitution.
[Okuyama, Tadashi; Fueno, Takayuki Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 10 p. 2672 - 2683]
The oxidation of 1, 2; 5, 6-di-O-isopropylidene-D-glucose by dimethyl sulfoxide-acetic anhydride
[Griesbaum, Karl; Zwick, Gerhard Chemische Berichte, 1985 , vol. 118, # 8 p. 3041 - 3057]