Generation of a solid Brønsted acid site in a chiral framework

MJ Ingleson, JP Barrio, J Bacsa, C Dickinson…

Index: Ingleson, Michael J.; Barrio, Jorge Perez; Bacsa, John; Dickinson, Calum; Park, Hyunsoo; Rosseinsky, Matthew J. Chemical Communications, 2008 , # 11 p. 1287 - 1289

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Citation Number: 115

Abstract

Zeolitic materials are important industrial heterogeneous catalysts, however their application in asymmetric transformations has been limited by the scarcity of chiral zeolite phases. 1,2 The requirement for new chiral porous catalytic materials may be fulfilled by metal organic frameworks (MOFs), with an increasing number of enantiopure materials reported, 3–6 including examples both porous and robust. 7–12 Excluding several notable exceptions, 13–15 realising both ...