An efficient procedure for the TEMPO-catalyzed oxidation of alcohols to aldehydes and ketones using ferric chloride hexahydrate as terminal oxidant

…, K Karthikeyan, PT Perumal

Index: Kumar, R. Senthil; Karthikeyan; Perumal, Paramasivan T. Canadian Journal of Chemistry, 2008 , vol. 86, # 7 p. 720 - 725

Full Text: HTML

Citation Number: 10

Abstract

A simple, efficient procedure for the oxidation of alcohols by catalytic 2, 2, 6, 6-tetramethyl- piperidyl-1-oxy (TEMPO) was developed using FeCl3⊙ 6H2O as the terminal oxidant. The reaction gives high yield of the corresponding aldehydes and ketones with no over oxidation to the acid. Key words: oxidation, TEMPO, FeCl3⊙ 6H2O.

Related Articles:

Diaryl pyrazole-4-carbaldehyde benzoylhydrazones metal complexes: Synthesis and their antibacterial and antioxidant screening

[Nasrullah, Muhammad; Khan, Misbahul Ain; Khan, Muhammad Naeem; Humphrey, Mark G. Humphrey; Nasim, Faizul Hassan; Chaudhry, Faryal; Abidi, Moeena Ghazal; Farooq, Umar; Munawar, Munawar Ali Asian Journal of Chemistry, 2013 , vol. 25, # 1 p. 419 - 423]

1, 3-Diphenylpyrazoles: synthesis and antiparasitic activities of azomethine derivatives

[European Journal of Medicinal Chemistry, , vol. 37, # 8 p. 671 - 679]

Novel, Mild, and Highly Efficient Method for the Synthesis of 2-Arylbenzothiazoles by the Oxidation of 2-Arylbenzothiazolines with Silicon Lewis Acids

[Synthetic Communications, , vol. 41, # 1 p. 136 - 146]

Synthesis of new heterocyclic hybrids based on pyrazole and thiazolidinone scaffolds as potent inhibitors of tyrosinase

[Bioorganic and Medicinal Chemistry, , vol. 21, # 10 p. 2772 - 2777]

1, 3-Diphenylpyrazoles: synthesis and antiparasitic activities of azomethine derivatives

[Rathelot, Pascal; Azas, Nadine; El-Kashef, Hussein; Delmas, Florence; Di Giorgio, Carole; Timon-David, Pierre; Maldonado, Jose; Vanelle, Patrice European Journal of Medicinal Chemistry, 2002 , vol. 37, # 8 p. 671 - 679]

More Articles...