Tunable Hydride Transfer in the Redox Amination of Indoline with Aldehyde: An Attractive Intramolecular Hydrogen??Bond Effect

H Mao, R Xu, J Wan, Z Jiang, C Sun…

Index: Mao, Hui; Xu, Runsheng; Wan, Jieping; Jiang, Zhengyang; Sun, Cuirong; Pan, Yuanjiang Chemistry - A European Journal, 2010 , vol. 16, # 45 p. 13352 - 13355

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Citation Number: 42

Abstract

Analogous to atom economy [1] and step economy,[2] redox economy has received considerable attention in modern organic synthesis, especially in the total synthesis of natural products since it was proposed by Baran in 2008.[3] Through using the inherent reducing power of hydrogen to reduce other functional groups, redox isomerizations can reduce the additional steps of oxidation or reduction.[3b] Moreover, selective CÀH bond ...

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