Arylation of several carbanions by the SRN1 mechanism
RA Rossi, JF Bunnett
Index: Rossi,R.A.; Bunnett,J.F. Journal of Organic Chemistry, 1973 , vol. 38, p. 3020 - 3025
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Citation Number: 56
Abstract
The carbanions derived from 1, 3-pentadiene, l-(p-anisyl) propene, indene, fluorene, 2- butanone, and 3-methyl-2-butanone are phenylated by treating them with bromobenzene and sodium or potassium metal in liquid ammonia. The enolate ions of the two ketones are also phenylated by photostimulated reaction with bromo-or iodobenxene. By either method, 2-butanone is phenylated principally at the 3 position and 3-methyl-2-butanone mainly at ...
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