Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
PC Too, YL Tnay, S Chiba
Index: Too, Pei Chui; Tnay, Ya Lin; Chiba, Shunsuke Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 1217 - 1225
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Citation Number: 8
Abstract
Abstract We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1, 5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon- centered radicals with molecular oxygen.
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