Journal of the American Chemical Society

Restricted Rotation in Aryl Amines. XXII. N-Benzenesulfonyl-N-carboxymethyl-3-amino-2, 4, 6-trimethylpyridine and its N-Oxide

R Adams, JE Dunbar

Index: Adams; Dunbar Journal of the American Chemical Society, 1958 , vol. 80, p. 3649

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Citation Number: 1

Abstract

N, N-dibenzenesulfonyl-3-amino-2, 4, 6-trimethylpyridine (V). When two moles of benzenesulfonyl chloride was used V was obtained in 79% yield. Compound V was in turn converted to N-benzene-sulfonyl-3-amino-2, 4, 6-trimethylpyridine (VI) by boiling with sodium ethoxide in ethanol sofution. Conversion of VI to N-benzenesulfonyl-N- carbomethoxymethyl-3-amino-2, 4, 6-trimethylpyridine was accomplished by treatment ...