Molecular rearrangements. 13. Kinetics and mechanism of rearrangements of some ring-substituted. alpha.-chlorostyrene oxides and trans-. beta.-chlorostyrene …
RN McDonald, RC Cousins
Index: McDonald, Richard N.; Cousins, Raymond C. Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 2976 - 2984
Full Text: HTML
Citation Number: 32
Abstract
The synthesis of certain phenyl-substituted derivatives of the isomeric trans-P-chlorostyrene oxides (6) and a-chlorostyrene oxides (7) are reported. The kinetics of rearrangement of 6 (X= p-CH3, H, p-Br, m-C1, p-NO,) to phenylchloroacetaldehydes (12) in CC14 buffered by Na2HP04 and 7 (X= p-CH3, H, p-NO,) to w-chloroacetophenones in CC14 were determined by following the rates of disappearance of the a-chloro epoxide and formation of the a- ...
Related Articles:
α??Chlorination of Acetophenones Using 1, 3??Dichloro??5, 5??Dimethylhydantoin
[Xu, Zijin; Zhang, Deyan; Zou, Xinzhuo Synthetic Communications, 2006 , vol. 36, # 2 p. 255 - 258]
[Zhu, Yan-Ping; Cai, Qun; Gao, Qing-He; Jia, Feng-Cheng; Liu, Mei-Cai; Gao, Meng; Wu, An-Xin Tetrahedron, 2013 , vol. 69, # 31 p. 6392 - 6398]
Synthesis and acid-catalyzed decomposition of o-nitrophenylsulfonyldiazomethane
[Wagenaar,A. et al. Journal of Organic Chemistry, 1974 , vol. 39, # 3 p. 411 - 414]
Facile synthesis of 2, 5??diacylthiophenes
[Miyahara,Y. Journal of Heterocyclic Chemistry, 1979 , vol. 16, p. 1147 - 1151]