Synthetic communications

Favorski Type Rearrangement in the Lead Tetraacetate Oxidation of Cycloalkanones

F Mathew, B Myrboh

Index: Mathew, Felix; Myrboh, Bekington Synthetic Communications, 1996 , vol. 26, # 6 p. 1097 - 1101

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Citation Number: 5

Abstract

Lead(1V) acetate has been used as a versat:ilr' ... Although tetralones have been shown to undergo ri,i~ij ... Earlier we had reported the successful use of lead(1V) ... General Procedure: In an optimized reacti.011 ... (a) All compounds were characterised by IR, 'H and I3C NMR . ... (b) Not isolated but converted directly into the ac'id by hydrolysis with 2(N) NaOH followed by acidification with con. HC1. ... 5OC. A solution of cyclohexanone (2g, 20 mmol) in

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