Tetrahedron

(N, N-Diisopropylcarbamoyloxy)-methyl p-tolyl sulfone: preparation and application for the syntheses of 1, 2-diols

L Ma, D Zhao, L Chen, X Wang, YL Chen, J Shen

Index: Ma, Lu; Zhao, Dongmei; Chen, Lin; Wang, Xin; Chen, Yue-Lei; Shen, Jingkang Tetrahedron, 2012 , vol. 68, # 42 p. 8704 - 8711

Full Text: HTML

Citation Number: 4

Abstract

1-(N, N-Diisopropylcarbamoyloxy)-1-tosyl-methane (CbOCH2Ts, Cb= N, N- diisopropylcarbamoyl) was readily prepared from p-TolSH, paraformaldehyde and CbCl. With the dual activation of CbO-and Ts-substitutions, deprotonation of CbOCH2Ts could be effected not only by n-BuLi, but also by Grignard reagents. Upon deprotonation, the title compound adds to various carbonyl structures. By choosing proper organometallic ...

Related Articles:

A novel and efficient catalytic epoxidation of olefins and monoterpenes with microencapsulated Lewis base adducts of methyltrioxorhenium

[Tetrahedron, , vol. 61, # 5 p. 1069 - 1075]

One-pot synthesis of enantiomerically pure 1, 2-diols: asymmetric reduction of aromatic α-oxoaldehydes catalysed by Candida parapsilosis ATCC 7330

[Mahajabeen, Pula; Chadha, Anju Tetrahedron Asymmetry, 2011 , vol. 22, # 24 p. 2156 - 2160]

Synthesis, characterization, catalytic and antiamoebic activity of vanadium complexes of binucleating bis (dibasic tridentate ONS donor) ligand systems

[European Journal of Inorganic Chemistry, , # 15 p. 2560 - 2577]

Mn (III) complexes of the monoprotic tridentate ONN donor 2-[2-(1H-(benzo [d] imidazol-2-yl) ethylimino) methyl] phenol as a functional mimic of haloperoxidase

[Polyhedron, , vol. 46, # 1 p. 33 - 40]

High pressure-promoted uncatalyzed hydrolysis of epoxides

[Kotsuki, Hiyoshizo; Kataoka, Masanori; Nishizawa, Hitoshi Tetrahedron Letters, 1993 , vol. 34, # 25 p. 4031 - 4034]

More Articles...