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As‐N and As‐N‐P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls
10.1002/ejic.201800109 2018-02-14 The isolation of binary As‐N and ternary As‐N‐P cage compounds consisting exclusively of group 15 elements was achieved by exploiting the reactivity of diarsadiazanediyl. This arsenic centered biradical is capable of activating and/or quenching small molecule... |
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One-Step In Situ Synthesis of Three-Dimensional NiSb Thin Films as Anode Electrode Material for the Advanced Sodium-Ion Battery
10.1002/ejic.201701362 2018-02-13 A low-cost, facile and highly efficient in situ solvothermal reaction has been developed for the first time to synthesize, by using a 3D Ni foam template, three-dimensional nickel-antimony (3D NiSb) thin films as anode electrode materials for use in sodium-io... |
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B12H122–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity
10.1002/ejic.201701206 2018-02-13 In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122– were synthesized and fully characterized. Two of these six complexes e... |
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Two Temperature-Controlled Zinc Coordination Polymers: Ionothermal Synthesis, Properties, and Dye Adsorption
10.1002/ejic.201701161 2018-02-13 Ionothermal reactions of Zn(NO3)2 with 1,2,4,5-benzenetetracarboxylic acid (H4BTeC) produced two temperature-controlled zinc(II) coordination polymers, [PMI]2[Zn2(BTeC)(H2BTeC)] (1) and [PMI]2[Zn3(BTeC)2]·2H2O (2; PMI = 1-methyl-3-propylimidazolium). The reac... |
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Cyclometalated ruthenium, osmium and iridium complexes bridged by NCN‐pyrene‐NCN derivative ‐ synthesis and characterization
10.1002/ejic.201800011 2018-02-12 New ruthenium (Ru), osmium (Os), and iridium (Ir) complexes bridged by cyclometalating 1,3,6,8‐tetra(4‐(2,2‐dimethylpropyloxy)‐2‐pyridyl)pyrene with terminal 4'‐(4‐metoxynaphthalene‐1‐yl)‐2,2':6',2''‐terpyridine ligands were synthesized and characterized to e... |
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Cyclopropylmagnesium scorpionates: a missing member in the series with both staggered and eclipsed rotamers in the crystal
10.1002/ejic.201800073 2018-02-12 The reaction of the hydrotris(3,5‐dimethylpyrazolyl)borate potassium salt KTpMe2 with [Mg(c‐C3H5)2(dioxane)x] gives [TpMe2Mg(c‐C3H5)] (1) in 70% yield. Full characterization includes an X‐ray diffraction study which reveals the presence of both staggered and ... |
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Catalytic H2 evolution with CoO, Co(OH)2 and CoO(OH) NPs generated from a molecular polynuclear Co complex
10.1002/ejic.201800033 2018-02-12 Electrochemical water reduction by employing first row transition metal nanoparticles (NPs) constitutes a sustainable way for the generation of H2. We have synthesized Co‐based NPs from a molecular CoII/CoIII precursor after its reductive decomposition at ‐1.... |
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1,2-Addition of Diethylzinc to a Bis(Imidazolyl)ketone Ligand
10.1002/ejic.201701363 2018-02-12 In this study, the selective 1,2-addition of diethylzinc to the ketone functionality of BMdiPhIK [bis(1-methyl-4,5-diphenylimidazolyl)ketone] is shown. The reaction product is isolated in a dimeric form with a planar Zn2(µ-O)2-motif keeping the two monomers t... |
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Synthesis, Substitution, and Oxidation of Imidazole-2-thione Based Tricyclic 1,4-Dihydro-1,4-diphosphinines
10.1002/ejic.201701338 2018-02-12 Herein, the synthesis and chemistry of P-functional tricyclic 1,4-dihydro-1,4-diphosphinines is described, following a recent communication on their use as precursors of 1,4-diphosphinines. In particular, ring formation of imidazole-2-thione-based tricyclic 1... |
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Controlling the Structures of Lanthanide Complexes in Self-Assemblies with Tripodal Ligands
10.1002/ejic.201800108 2018-02-12 Abstract Invited for the cover of this issue is Josef Hamacek from CNRS Orléans, France. The cover image shows the spontaneous self-assembly of tripodal ligands and lanthanide cations. A deep understanding of fundamental aspects of self-assembly opens the way... |