Disulfanyl(dithioxo)tungsten diammoniate

Modify Date: 2026-07-04 12:18:31

Disulfanyl(dithioxo)tungsten diammoniate Structure
Disulfanyl(dithioxo)tungsten diammoniate structure
Common Name Disulfanyl(dithioxo)tungsten diammoniate
CAS Number 13862-78-7 Molecular Weight 348.177
Density 2.71 g/mL at 25 °C(lit.) Boiling Point N/A
Molecular Formula H8N2S4W Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Summary: Ammonium tetrathiotungstate (CAS号:13862-78-7),molecular formula:H8N2S4W,molecular weight:348.177. For research-use only, not for medical or clinical usage.


 Names

This table lists Chinese names, IUPAC names and various aliases of this chemical substance.

Name ammonium tetrathiotungstate
Synonym More Synonyms

 Chemical & Physical Properties

This table shows physicochemical parameters including melting point, boiling point, density, solubility and optical rotation. Missing data is marked as N/A.

Density 2.71 g/mL at 25 °C(lit.)
Molecular Formula H8N2S4W
Molecular Weight 348.177
Exact Mass 347.907928
PSA 148.26000
LogP 2.70520

 MSDS

This table provides MSDS information including hazard classification, first‑aid, fire‑fighting, spill handling, operation and storage instructions.


Section 1: Product Identification
Chemical Name:Ammonium tetrathiotungstate (VI), 99% (99.9+%-W)
CAS Registry Number:13862-78-7
Formula:(NH4)2WS4
EINECS Number:none
Chemical Family:metal tungstate
Synonym:Ammonium thiotungstate (VI)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound13862-78-7100%1g/m3 (as W - soluble)no data

Section 3: Hazards Identification
Emergency Overview:Dust is irritating to eyes, skin and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:Irritating to eyes. May cause redness and pain.
Skin Contact:Mildly irritating to skin. May cause itching and redness.
Inhalation:Inhalation of dust can lead to irritation of the respiratory tract, causing coughing and sore throat.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-combustible.
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, choking fumes of sulfur dioxide may form.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective gloves and clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow to orange xtl.
Molecular Weight:348.18
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:rotten egg odor
Solubility in Water:1g/15cc (turbid solution)

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:reaction with mineral acids
Incompatibility:Strong oxidizing agents and mineral acids
Decomposition Products:ammonia, nitrogen oxides, sulfur dioxide and tungsten compounds.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

This table covers safety warnings, protective measures, incompatible substances and disposal guidelines for this compound.

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR UN 3335
WGK Germany 3

 Synthetic Route

This table presents publicly reported synthetic routes, reaction conditions, reactants and product information of the compound.

~82%

Disulfanyl(dithioxo)tungsten diammoniate Structure

Disulfanyl(dith...

CAS#:13862-78-7

Learn More
Literature: Drew, Michael G. B.; Hobson, Richard J.; Mumba, Peter P. E. M.; Rice, David A.; Turp, Neil Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 1163 - 1168

 Precursor & DownStream

This table lists upstream starting materials and downstream derivative products related to this chemical.

Precursor  2

DownStream  1

 Articles6

More Articles

This table lists relevant public references with title, journal and publication metadata for this compound.

Heterogeneous WSx/WO₃ Thorn-Bush Nanofiber Electrodes for Sodium-Ion Batteries.

ACS Nano 10 , 3257-66, (2016)

Heterogeneous electrode materials with hierarchical architectures promise to enable considerable improvement in future energy storage devices. In this study, we report on a tailored synthetic strategy...

Behavior of [185W]thiotungstates injected into sheep and the influence of copper: their fate and the effect of the compounds upon plasma copper.

J. Inorg. Biochem. 35(2) , 115-26, (1989)

[185W]trithio- and tetrathiotungstates (0.5 mg W) were injected intravenously into sheep. The compounds circulated in plasma bound reversibly to plasma proteins, particularly to albumin. After the fir...

Antitumor and antiinflammatory effects of tetrathiotungstate in comparison with tetrathiomolybdate.

Transl. Res. 149(5) , 260-4, (2007)

Tetrathiomolybdate (TM) is an anticopper drug under development for treating Wilson's disease. Its mechanism of action involves forming a tight tripartite complex in the blood with serum albumin and a...

 Synonyms

This table collects all English aliases, systematic names and CAS‑related synonyms of the compound.

azane,bis(sulfanylidene)tungsten,sulfanide
Ammonium tetrathiotungstate
Disulfanyl(dithioxo)tungsten diammoniate
Tungsten, dimercaptodithioxo-, ammonium salt
MFCD00061410

 Disulfanyl(dithioxo)tungsten diammoniate | FAQ

This section contains frequently‑asked‑questions about this compound, including basic parameters, properties, storage conditions and corresponding answers.

Q: What is the molecular formula of ammonium tetrathiotungstate?
A: Molecular formula of ammonium tetrathiotungstate is H8N2S4W.
Q: What is the safety information for ammonium tetrathiotungstate?
A: Safety information for ammonium tetrathiotungstate: S26-S37/39.
Q: What are the upstream materials of ammonium tetrathiotungstate?
A: Related upstream materials(CAS) of ammonium tetrathiotungstate: 10213-10-2;7783-06-4.
Q: What is the polar surface area (PSA) of ammonium tetrathiotungstate?
A: Polar surface area (PSA) of ammonium tetrathiotungstate is 148.26000.
Q: What English synonyms does ammonium tetrathiotungstate have?
A: English synonyms of ammonium tetrathiotungstate: azane,bis(sulfanylidene)tungsten,sulfanide, Ammonium tetrathiotungstate, Disulfanyl(dithioxo)tungsten diammoniate, Tungsten, dimercaptodithioxo-, ammonium salt, MFCD00061410.
Q: What is the English name of ammonium tetrathiotungstate?
A: The English name of ammonium tetrathiotungstate is ammonium tetrathiotungstate.
Q: What is the CAS number of ammonium tetrathiotungstate?
A: CAS number of ammonium tetrathiotungstate is 13862-78-7.
Q: What is the LogP of ammonium tetrathiotungstate?
A: LogP of ammonium tetrathiotungstate is 2.70520.
Q: What are the downstream products of ammonium tetrathiotungstate?
A: Related downstream products(CAS) of ammonium tetrathiotungstate: 7440-33-7.
Q: What is the molecular weight of ammonium tetrathiotungstate?
A: Molecular weight of ammonium tetrathiotungstate is 348.177.

 Disulfanyl(dithioxo)tungsten diammoniatefactory

This table lists manufacturers and suppliers of this compound, including vendor names and product supply reference information.

Shanghai Nianxing Industrial Co., Ltd
Dayang Chem (Hangzhou) Co., Ltd.
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