Anti-Markonikov Reactions, 6.-Rhodium-Catalyzed Amination of Vinylpyridines: Hydroamination versus Oxidative Amination

…, H Trauthwein, M Eichberger, C Breindl…

Index: Beller, Matthias; Trauthwein, Harald; Eichberger, Martin; Breindl, Claudia; Mueller, Thomas E. European Journal of Inorganic Chemistry, 1999 , # 7 p. 1121 - 1132

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Citation Number: 56

Abstract

Introduction reaction of vinylpyridines. Additional interest in these reac-The construction of carbonnitrogen bonds by using tions results from the fact that 2-(2-aminoethyl) pyridines transition metal catalysts, especially for the synthesis of are used as building blocks for pharmaceuticals and fine amines, has become an area of intensive research. Catalytic chemicals for hydrometallurgy.[4] aminations of olefins [2] to selectively give primary, ...