e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Reactions of benzoyl (carbonyl) transition metal complexes with LiNMe2: on the feasibility of a reaction route to α-keto amide through an acyl (carbamoyl) cobalt …
Abstract CO-coordinated benzoyltransition metal complexes, PhCOCo (CO) 3 L (L PPh 3, PCy 3, and PMe 3), PhCOMn (CO) 5, have been prepared and their reactions with LiNMe 2 examined. The reactions give α-keto amide (PhCO-CONMe 2) after treating the systems with Br 2 or organic halides.
[Ozawa, Fumiyuki; Soyama, Hidehiko; Yanagihara, Hisayoshi; Aoyama, Issei; Takino, Hiroaki; et al. Journal of the American Chemical Society, 1985 , vol. 107, # 11 p. 3235 - 3245]
