Journal of catalysis

Bifunctional iridium-(2-aminoterephthalate)–Zr-MOF chemoselective catalyst for the synthesis of secondary amines by one-pot three-step cascade reaction

M Pintado-Sierra, AM Rasero-Almansa, A Corma…

Index: Pintado-Sierra, Mercedes; Rasero-Almansa, Antonia M.; Corma, Avelino; Iglesias, Marta; Sanchez, Felix Journal of Catalysis, 2013 , vol. 299, p. 137 - 145

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Citation Number: 71

Abstract

A simple and efficient method for the synthesis of N-alkyl amines via a cascade reaction (hydrogenation+ reductive amination) using a new recyclable hybrid catalyst that combines the catalytic power of transition metal complexes with the architecture of metal organic frameworks (MOFs).