Chemistry–A European Journal

Chemoselective Synthesis of Substituted Imines, Secondary Amines, and β??Amino Carbonyl Compounds from Nitroaromatics through Cascade Reactions on Gold …

LL Santos, P Serna, A Corma

Index: Santos, Laura L.; Serna, Pedro; Corma, Avelino Chemistry - A European Journal, 2009 , vol. 15, # 33 p. 8196 - 8203

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Citation Number: 52

Abstract

Abstract Substituted imines, α, β-unsaturated imines, substituted secondary amines, and β- amino carbonyl compounds have been synthesized by means of new cascade reactions with mono-or bifunctional gold-based solid catalysts under mild reaction conditions. The related synthetic route involves the hydrogenation of a nitroaromatic compound in the presence of a second reactant such as an aldehyde, α, β-unsaturated carbonyl compound ...