Amine Exchange Reactions. Mannich Bases from Aromatic Amines1

JC Craig, M Moyle, LF Johnson

Index: Craig,J.C. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 410 - 415

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Citation Number: 45

Abstract

Treatment of 1-t-Octylaminomethyl-&naphthol (IIIg) with Hot Ethanol.-lt-Octylaminomethyl-2- naphthol (2.5 g.) was warmed to 50-.%'in 30 ml. of 95y0 ethanol for 5 min. and then kept at room temperature for 2 days. Removal of the solvents under reduced pressure gave an oil which was dissolved in 100 ml. of ether. The resulting solution was extracted with 100 ml. of water containing 2 g. of sodium hydroxide. The ether extract was washed with water and ...