Applied Catalysis A: General

Oxidation of amines over alumina based catalysts

K Rakottyay, A Kaszonyi, S Vajíček

Index: Rakottyay, Karol; Kaszonyi, Alexander; Vajicek, Stanislav Applied Catalysis A: General, 2010 , vol. 378, # 1 p. 33 - 41

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Citation Number: 9

Abstract

Amines were oxidized by molecular oxygen in the vapor phase at atmospheric pressure over alumina and silicotungstic acid/alumina catalysts. The study is focused on the influence of structure of amine and catalyst properties on the composition of the main reaction products and byproducts. Coating of γ-Al2O3 with silicotungstic acid or its semisalt can significantly enhance its catalytic activity in amine oxidation. The adsorption of amine on ...