Organic Letters 2011-02-18

Vinyl diazophosphonates as precursors to quaternary substituted indolines and cyclopentenes.

Jin Wang, Vyacheslav Boyarskikh, Jon D Rainier

Index: Org. Lett. 13(4) , 700-2, (2011)

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Abstract

Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C-H insertion reactions or sulfonium ylide rearrangements when exposed to Rh(2)(OAc)(4).