Chemical Communications 2007-04-21

Phosphine containing oligonucleotides for the development of metallodeoxyribozymes.

Loïc Ropartz, Nico J Meeuwenoord, Gijsbert A van der Marel, Piet W N M van Leeuwen, Alexandra M Z Slawin, Paul C J Kamer

Index: Chem. Commun. (Camb.) (15) , 1556-8, (2007)

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Abstract

Novel transition metal catalysts based on oligonucleotides can be easily obtained by functionalization of 5-iodouridine with phosphine ligands, resulting in good asymmetric induction in palladium catalyzed allylic nucleophilic substitution.