Journal of the American Chemical Society

Oxidation of hydroquinone silyl ethers to quinones

RF Stewart, LL Miller

Index: Stewart, Ray F.; Miller, Larry L. Journal of the American Chemical Society, 1980 , vol. 102, # 15 p. 4999 - 5004

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Citation Number: 49

Abstract

Abstract: The electrochemical oxidation of trialkylsiloxybenzene derivatives was investigated using platinum and graphite anodes in either acetonitrile or methylene chloride solvent. Preparative oxidation of the bis (trimethylsily1) ethers of hydroquinone, chlorohydroquinone, 2, 5-di-tert-butylhydroquinone, and 9, lO-dihydroxyanthracene gave the corresponding quinones in 80-90% yield. Oxidation of 1, 4-bis (trimethylsiloxy)-2-methoxybenzene in ...