Synthesis and evaluation of lipophilic BTBP ligands for An/Ln separation in nuclear waste treatment: the effect of alkyl substitution on extraction properties and …

…, P Distler, J John, K Stamberg, A Núñez…

Index: Lewis, Frank W.; Harwood, Laurence M.; Hudson, Michael J.; Distler, Petr; John, Jan; Stamberg, Karel; Nunez, Ana; Galan, Hitos; Espartero, Amparo G. European Journal of Organic Chemistry, 2012 , # 8 p. 1509 - 1519

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Citation Number: 21

Abstract

Abstract Four new 6, 6′-bis (1, 2, 4-triazin-3-yl)-2, 2′-bipyridine (BTBP) ligands, which contain either additional alkyl groups on the pyridine rings or seven-membered aliphatic rings attached to the triazine rings, have been synthesized, and the effects of the additional alkyl substitution in the 4-and 4′-positions of the pyridine rings on their extraction properties with Ln III and An III cations in simulated nuclear waste solutions have been ...