The Journal of Organic Chemistry

Alkaline Degradation of 1, 1-Disubstituted Sulfonhydrazides. Synthesis of a Pair of Cyclic, Benzylic Hydrazines Derived from Acenaphthene and Acenaphthylene1

LA Carpino, S Göwecke

Index: Carpino,L.A.; Goewecke,S. Journal of Organic Chemistry, 1964 , vol. 29, p. 2824 - 2830

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Citation Number: 20

Abstract

In order to test some hypotheses relating to the oxidation and sulfonhydrazide degradation of 1, l-disubstituted hydrazines two appropriate model hydrazines have been prepared for further study, namely 2-amino-2, 3-dihydro-1H-indeno [1, 6, 7-def] isoquinoline (111) and 2- amino-2, 3, 6, 7-tetrahydro-lH-indeno [1, 6, 7-def] isoquinoline (11). Treatment of acenaphthene-5, 6-dicarboxylic acid anhydride with hydrazine hydrate gave the ...