Journal of the American Chemical Society

The condensation of sulfoxides with p-toluenesulfonamide and substituted acetamides

DS Tarbell, C Weaver

Index: Tarbell; Weaver Journal of the American Chemical Society, 1941 , vol. 63, p. 2939,2942

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Citation Number: 79

Abstract

Clarke, Kenyon and Phillips3 proposed the much more plausible formula, I, in which the sulfur is attached to nitrogen by a coordinate bond; they supported this formula by showing that m-carboxyphenyl-methylsulfin-p-toluenenesulfonylimine (I, R'= m-CsH&OOH, R”= CHI) could be resolved, similar to unsymmetrical sulfoxides and to sulfinic esters. Since these compounds are known to have coordinate links between sulfur and oxygen, the ...