Journal of chemical research

The effective preparation of secondary amines bearing a vinylsilane functionality via the reaction of primary amines with α-chlorine-substituted allylsilanes catalysed …

M Kozuka, M Mitani

Index: Kozuka, Makoto; Mitani, Michiharu Journal of Chemical Research, 2007 , # 8 p. 464 - 467

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Abstract

The reaction of α-chlorine-substituted allylsilanes with primary amines was promoted by CuCl to result in the selective formation of secondary amines bearing the vinylsilane functionality by a probable SN2'-allylation keeping the silyl group intact. ... Keywords: vinylsilane, allylsilane, copper catalyst, secondary amine ... The preparation of secondary amines has commonly been accomplished by the reactions of primary amines with a range of electrophiles ...