Synthesis of Furoates and Furfurylic Alcohol Esters Under Very Mild Conditions Using Supported Base Catalysis

…, M Delmas, JP Gorrichon, A Gaset

Index: Le Bigot, Yves; Delmas, Michel; Gorrichon, Jean-Pierre; Gaset, Antoine Synthetic Communications, 1982 , vol. 12, # 4 p. 327 - 332

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Abstract

A dehydrohalogenation side reaction markedly decreases the yield in the esters obtained from a carboxylate ion and a halogenated derivative in alkaline media (1). This drowback can however be avoided in phase transfer catalysis as the carboxylate ion is suspended in the organic solvent containing the halogenated derivative (1).

~92%

~78%

~96%

~92%

~92%

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