Journal of the American Chemical Society 2008-08-20

Block copolymer-like self-assembly of fluorocarbon end-functionalized polystyrene and polybutylmethacrylate.

Jingguo Shen, Thieo Hogen-Esch

Index: J. Am. Chem. Soc. 130(33) , 10866-7, (2008)

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Abstract

We demonstrate the self-assembly through fluorophilic interactions of a blend of perfluorocarbon (RF) end-functionalized polystyrene and the corresponding RF-polybutylmethacrylate into optically transparent materials that retain domain characteristics typical of the component polymers but show well-defined lamellar nanostructured morphologies that qualitatively resemble that of the corresponding block copolymers.