Fluorination of Hydrogen-containing with elemental fluorine

…, GP Gambaretto, M Napoli, C Gervasutti

Index: Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C. Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326

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Citation Number: 6

Abstract

Abstract The hydrohalo-olefins cis and trans CHC1= CHC1, CHC1= CC1 2, CHC1= CH-CH 2 C1 and CH 2= CC1-CH 2 C1 have been fluorinated with elemental fluorine to give good yields of hydrohalofluoroalkanes. The best operational conditions for F 2 addition to the double bond rather than hydrogen and/or chlorine atom substitution, dimerization and oligomerization of radical intermediates have been studied. Preliminary studies on the ...