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Aqueous organotin chemistry: Tin hydride mediated dehalogenation of organohalides and a novel organotin mediated nucleophilic substitution on 2-iodobenzoates in …

KD Sarma, U Maitra

Index: Sarma, Koushik Das; Maitra, Uday Tetrahedron, 1998 , vol. 54, # 19 p. 4965 - 4976

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Citation Number: 20

Abstract

This paper describes the dehalogenation of water soluble and water insoluble organohalides in water by tri-n-butyltin hydride (TBTH), preformed TBTH and triphenyltin hydride (TPTH) in water. TBTH in the presence of a radical trap, and Ph4Sn were also found to effect nucleophilic substitution of 2-iodobenzoates in the presence of various nucleophiles.