Microwave-assisted silica-supported aluminum chloride-catalyzed Friedel-Crafts alkylation

…, VL Campanella, DAM Rudzinski, F Beland, R Priefer

Index: Zupp, Laurine R.; Campanella, Veronica L.; Rudzinski, Diandra M.; Beland, Franois; Priefer, Ronny Tetrahedron Letters, 2012 , vol. 53, # 39 p. 5343 - 5346

Full Text: HTML

Citation Number: 5

Abstract

Microwave irradiation is a popular method in organic synthesis to achieve high yields in shorter reaction times. This decreases total 'man-hours' in a synthetic setting. Another technique used in organic chemistry to decrease manual manipulations, is solid support reagents. The benefits of this approach is that upon completion of a reaction, a simple filtration can be performed which expedites the work-up and also produces less organic ...

 Related Synthetic Route
Toluene Structure

108-88-3

Toluene

2-Bromopropane Structure

75-26-3

2-Bromopropane

~75%

p-cymene Structure

99-87-6

p-cymene

1-Bromobutane Structure

109-65-9

1-Bromobutane

Toluene Structure

108-88-3

Toluene

~%

1-methyl-4-(1-methylpropyl)benzene Structure

1595-16-0

1-methyl-4-(1-m...

4-n-butyltoluene Structure

1595-05-7

4-n-butyltoluene

2-Bromo-2-methylpropane Structure

507-19-7

2-Bromo-2-methy...

Chlorobenzene Structure

108-90-7

Chlorobenzene

~58%

1-tert-Butyl-4-chlorobenzene Structure

3972-56-3

1-tert-Butyl-4-...

1-Bromopentane Structure

110-53-2

1-Bromopentane

benzene Structure

71-43-2

benzene

~%

n-Amylbenzene Structure

538-68-1

n-Amylbenzene

2-phenylpentane Structure

2719-52-0

2-phenylpentane

Detail
1-Bromopentane Structure

110-53-2

1-Bromopentane

benzene Structure

71-43-2

benzene

~%

n-Amylbenzene Structure

538-68-1

n-Amylbenzene

2-phenylpentane Structure

2719-52-0

2-phenylpentane

Detail
Chlorobenzene Structure

108-90-7

Chlorobenzene

2-Bromopropane Structure

75-26-3

2-Bromopropane

~%

2-chlorocumene Structure

2077-13-6

2-chlorocumene

4-chlorocumene Structure

2621-46-7

4-chlorocumene

2-Bromobutane Structure

78-76-2

2-Bromobutane

Toluene Structure

108-88-3

Toluene

~%

1-methyl-4-(1-methylpropyl)benzene Structure

1595-16-0

1-methyl-4-(1-m...

1-sec-Butyl-2-methylbenzene Structure

1595-06-8

1-sec-Butyl-2-m...

2-Bromobutane Structure

78-76-2

2-Bromobutane

Toluene Structure

108-88-3

Toluene

~66%

1-methyl-4-(1-methylpropyl)benzene Structure

1595-16-0

1-methyl-4-(1-m...

1-Bromobutane Structure

109-65-9

1-Bromobutane

Toluene Structure

108-88-3

Toluene

~%

1-methyl-4-(1-methylpropyl)benzene Structure

1595-16-0

1-methyl-4-(1-m...

4-n-butyltoluene Structure

1595-05-7

4-n-butyltoluene

2-Bromobutane Structure

78-76-2

2-Bromobutane

Toluene Structure

108-88-3

Toluene

~%

1-methyl-4-(1-methylpropyl)benzene Structure

1595-16-0

1-methyl-4-(1-m...

1-sec-Butyl-2-methylbenzene Structure

1595-06-8

1-sec-Butyl-2-m...

1-Bromopropane Structure

106-94-5

1-Bromopropane

benzene Structure

71-43-2

benzene

~60%

Cumene Structure

98-82-8

Cumene

2-Bromo-2-methylpropane Structure

507-19-7

2-Bromo-2-methy...

Toluene Structure

108-88-3

Toluene

~88%

tbt Structure

98-51-1

tbt

2-Bromobutane Structure

78-76-2

2-Bromobutane

Chlorobenzene Structure

108-90-7

Chlorobenzene

~%

1-Chloro-4-(1-methylpropyl)benzene Structure

36383-14-9

1-Chloro-4-(1-m...

1-butan-2-yl-2-chlorobenzene Structure

36383-12-7

1-butan-2-yl-2-...

2-Bromobutane Structure

78-76-2

2-Bromobutane

Chlorobenzene Structure

108-90-7

Chlorobenzene

~%

1-Chloro-4-(1-methylpropyl)benzene Structure

36383-14-9

1-Chloro-4-(1-m...

1-butan-2-yl-2-chlorobenzene Structure

36383-12-7

1-butan-2-yl-2-...

2-Bromobutane Structure

78-76-2

2-Bromobutane

benzene Structure

71-43-2

benzene

~92%

sec-Butylbenzene Structure

135-98-8

sec-Butylbenzene


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved