Tetrahedron

Rhodium-catalyzed addition of arylstannanes to carbon–heteroatom double bond

S Oi, M Moro, H Fukuhara, T Kawanishi, Y Inoue

Index: Oi, Shuichi; Moro, Mitsutoshi; Fukuhara, Hiroe; Kawanishi, Takanori; Inoue, Yoshio Tetrahedron, 2003 , vol. 59, # 24 p. 4351 - 4361

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Citation Number: 55

Abstract

The addition of arylstannanes to the carbon–heteroatom double bond in the presence of a catalytic amount of a cationic rhodium complex ([Rh (cod)(MeCN) 2] BF4) was examined. The reactions of aldehydes, α-dicarbonyl compounds, and N-substituted aldimines with the arylstannanes gave corresponding alcohols, α-hydroxy carbonyl compounds, and amines, respectively. An arylrhodium complex generated by the transmetalation with the ...

934-56-5

TRIMETHYL(PHENYL)TIN

~60%

~88%

~85%

~79%

~66%

~58%

~74%

~85%

~60%

~43%

~76%

~54%

~96%

~96%

~29%

~31%

~47%

~92%

~90%

~85%

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