Orbital-overlap factor in electron transfer: sensitivity of homogeneous self-exchange kinetics for some metallocenes to electronic structure

RM Nielson, MN Golovin, GE McManis…

Index: Journal of the American Chemical Society, , vol. 110, # 6 p. 1745 - 1749

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Citation Number: 51

Abstract

... Experimental Section Cobaltocene was obtained from Strem Chemicals. ... 0 1988 American Chemical Society Page 2. ... described by Wahl et aL6 were used to extract the desired rate constants for homogeneous self-exchange, ea, by employing the measured chemical shifts and ...