Journal of Physical Organic Chemistry

Solvatochromism of catechol derivatives–solute/solvent interactions

F Riedel, S Spange

Index: Riedel, Franziska; Spange, Stefan Journal of Physical Organic Chemistry, 2012 , vol. 25, # 12 p. 1261 - 1268

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Citation Number: 9

Abstract

Abstract The solvatochromism of nine push–pull substituted catechol derivatives has been studied in a set of 39 various solvents. The influence of successive methyl substitution at the catechol OH groups on the extent of the solvatochromic shift has been investigated. The positive solvatochromism of 2-(3, 4-dihydroxybenzylidene)-2H-indene-1, 3-dione amounts 4360 cm–1, which ranges from toluene to hexamethyl-phosphoric triamide. To the best of ...