Analytical Sciences 2012-01-01

Cold-spray ionization mass spectrometric detection of a coordination oligomer.

Kazuaki Ohara, Kentaro Yamaguchi

Index: Anal. Sci. 28(7) , 635-7, (2012)

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Abstract

Coordination polymer (CP) formation is an unexplored area in weak-interaction chemistry due to the difficulty of monitoring the coordination process. By using cold-spray ionization mass spectrometry (CSI-MS), several kinds of coordination compounds were detected when CuI metal and the 4,7-phenanthroline organic bridged ligand were mixed in solution. The observed ion peaks could be reasonably and simply assigned to various combinations of the metal and the ligand without any fragmentation.