The Journal of Organic Chemistry

Dimethyldioxirane oxidation of primary amines

JK Crandall, T Reix

Index: Crandall, Jack K.; Reix, Thierry Journal of Organic Chemistry, 1992 , vol. 57, # 25 p. 6759 - 6764

Full Text: HTML

Citation Number: 63

Abstract

1 2 6 a: R1. Rz=(CH) sb: R,= n CIH,. b,= H poesible and dimerization is facilitated relative to the aryl and tertiary alkyl analogs that were intermediatea in most of the reported examples using law The oxidation of cyclohexylamine (2a) by 1 was examined in some detail. Reactions were normally performed by adding an excess of the oxidant solution in several portions to a solution of 2a until the starting amine was consumed, usually less than 0.5 h. ...