Chemical Communications

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

A Kondoh, TF Jamison

Index: Kondoh, Azusa; Jamison, Timothy F. Chemical Communications, 2010 , vol. 46, # 6 p. 907 - 909

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Citation Number: 28

Abstract

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki–Miyaura cross-coupling applications are also presented.

 Related Synthetic Route
Cyclopentene Structure

142-29-0

Cyclopentene

Bis(pinacolato)diboron Structure

73183-34-3

Bis(pinacolato)...

~%

2-cyclopentyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Structure

66217-55-8

2-cyclopentyl-4...

1-Cyclopentenylboronic acid pinacol ester Structure

287944-10-9

1-Cyclopentenyl...

4-Bromotoluene Structure

106-38-7

4-Bromotoluene

Cyclohexene-1-boronic acid pinacol ester Structure

141091-37-4

Cyclohexene-1-b...

~%

1-(1-cyclohexenyl)-4-methyl-benzene Structure

1821-23-4

1-(1-cyclohexen...


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