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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Chemische Berichte

Carbonyl diisocyanate: A new preparation and some reactions

B Akteries, JC Jochims

Index: Akteries, Bernhard; Jochims, Johannes C. Chemische Berichte, 1986 , vol. 119, # 1 p. 83 - 95

Full Text: HTML

Citation Number: 13

Abstract

Abstract A preparation of carbonyl diisocyanate (2) from tri-n-butyltin isocyanate (4) and phosgene is reported. Correspondingly, the acyl isocyanates 6 were obtained from 4 with acyl chlorides. On standing, carbonyl diisocyanate trimerizes reversibly to the triazine 9, ...

 Related Synthetic Route
phosgene Structure

75-44-5

phosgene

tri-n-butylisocyanatotin Structure

681-99-2

tri-n-butylisoc...

~0%

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

Chlorotributyltin Structure

1461-22-9

Chlorotributyltin

1,3,5-tris(isocyanatocarbonyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione Structure

74072-68-7

1,3,5-tris(isoc...

~89%

Tricyanic acid Structure

108-80-5

Tricyanic acid

Methanol Structure

67-56-1

Methanol

1,3,5-tris(isocyanatocarbonyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione Structure

74072-68-7

1,3,5-tris(isoc...

~0%

Tricyanic acid Structure

108-80-5

Tricyanic acid

dimethyl imidodicarboxylate Structure

51216-94-5

dimethyl imidod...

phosgene Structure

75-44-5

phosgene

symclosene Structure

87-90-1

symclosene

~81%

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

phosgene Structure

75-44-5

phosgene

tri-n-butylisocyanatotin Structure

681-99-2

tri-n-butylisoc...

~58%

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

phosgene Structure

75-44-5

phosgene

tri-n-butylisocyanatotin Structure

681-99-2

tri-n-butylisoc...

~60%

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

Chlorotributyltin Structure

1461-22-9

Chlorotributyltin

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

~88%

2H-1,3,5-Oxadiazine-2,4,6(3H,5H)-trione Structure

6498-11-9

2H-1,3,5-Oxadia...

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

Benzylamine hydrochloride Structure

3287-99-8

Benzylamine hyd...

~82%

1-benzyl-1,3,5-triazinane-2,4,6-trione Structure

23097-87-2

1-benzyl-1,3,5-...

carbonyl diisocyanate Structure

6498-10-8

carbonyl diisoc...

Methylamine hydrochloride Structure

593-51-1

Methylamine hyd...

~67%

1-methyl-1,3,5-triazinane-2,4,6-trione Structure

6726-47-2

1-methyl-1,3,5-...

tri-n-butylisocyanatotin Structure

681-99-2

tri-n-butylisoc...

Acetyl chloride Structure

75-36-5

Acetyl chloride

~59%

acetyl isocyanate Structure

3998-25-2

acetyl isocyanate

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Detail Synthetic Route


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