Synthesis of Nonracemic α??Trifluoromethyl α??Amino Acids from Sulfinimines of Trifluoropyruvate

A Asensio, P Bravo, M Crucianelli…

Index: European Journal of Organic Chemistry, , # 8 p. 1449 - 1458

Full Text: HTML

Citation Number: 36

Abstract

... Issue. European Journal of Organic Chemistry. ... J. Org. ... The stereocontrolled synthesis of nonracemic quaternary α,α-disubstituted α-amino acids (C α,α -AAs) represents an attractive target in modern organic chemistry, because incorporation of C α,α -AAs into peptides imposes ...

 Related Synthetic Route
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

~%

L-Menthol Structure

2216-51-5

L-Menthol

4-Methylbenzenesulfinamide Structure

188447-91-8

4-Methylbenzene...

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

216855-44-6

N/A

~78%

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

(R)-α-trifluoromethylphenylalanine methyl ester Structure

184636-51-9

(R)-α-trifluoro...

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

~%

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

4-Methylbenzenesulfinamide Structure

188447-91-8

4-Methylbenzene...

~%

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

N-(p-tolylsulfinylimino)triphenylphosphorane Structure

216855-39-9

N-(p-tolylsulfi...

~%

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

D-Menthol Structure

15356-60-2

D-Menthol

methyl 2-benzyl-3,3,3-trifluoro-2-((R)-4-methylphenylsulfinamido)propanoate Structure

343257-00-1

methyl 2-benzyl...

~%

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate Structure

91796-57-5

(1S,2R,5S)-(+)-...

methyl 2-amino-2-benzyl-3,3,3-trifluoropropanoate Structure

184636-50-8

methyl 2-amino-...

PYRROLINE Structure

247089-85-6

PYRROLINE

~%

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate Structure

91796-57-5

(1S,2R,5S)-(+)-...

N-(p-tolylsulfinylimino)triphenylphosphorane Structure

334023-36-8

N-(p-tolylsulfi...

~%

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate Structure

91796-57-5

(1S,2R,5S)-(+)-...

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure

1517-82-4

(1R,2S,5R)-(-)-...

~%

L-Menthol Structure

2216-51-5

L-Menthol

4-Methylbenzenesulfinamide Structure

188447-91-8

4-Methylbenzene...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved