Direct preparation of lanthanoid ester homoenolates from 3-halo esters and lanthanoid metals: their homo-Reformatskii type reaction with carbonyl compounds

S Fukuzawa, N Sumimoto, T Fujinami…

Index: Journal of Organic Chemistry, , vol. 55, # 5 p. 1628 - 1631

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Citation Number: 26

Abstract

... g Acetophenone was added to the organosamarium reagent at -78 "C. The chemistry of metal homoenolates (P-metal-substi- tuted carbonyl compounds) has been rapidly advanced, especially aiming at their use in organic synthesis, leading to ... J. Org. Chem., Vol. 55, No. ...