Use of Alkene Chloronium Intermediates in Organic Synthesis. Two New Reactions of Alkene Chloronium Ions

G Sumrell, RG Howell, BM Wyman…

Index: Sumrell,G. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 84 - 88

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Citation Number: 2

Abstract

A number of new chlorinated esters and ethers and one new amide have been prepared utilizing" three-component reactions" involving an olefin, chlorine, and a third material capable of reacting with the intermediate chloronium ion. Two hitherto unreported reactions of alkene chloronium ions were noted and investigated. They were (1) cleavage of the ether linkage, and (2) substitution of the benzene nucleus.

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