Journal of Organic Chemistry 2012-07-06

Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions.

Richard J Delley, AnnMarie C O'Donoghue, David R W Hodgson

Index: J. Org. Chem. 77(13) , 5829-31, (2012)

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Abstract

We report the pH-k(obs) profiles for the hydrolyses of phosphodichloridate and thiophosphodichloridate ions in aqueous solutions. Both species show broad pH-k(obs) plateaus that extend to high pHs.